What is Pokémon Masters EX?
Pokémon Masters EX is a mobile strategy RPG where trainers battle using sync pairs—a combination of a Pokémon and its trainer. Players assemble teams and strategise based on their abilities, types, and synergy.
Importance of Tier Lists in Pokémon Masters EX

Since the game features a vast number of sync pairs, a Pokémon Masters EX Tier List helps players choose the best combinations for different battle scenarios.
How Tier Lists Are Created and Updated
The rankings are based on factors like base stats, move effectiveness, synergy potential, and overall versatility in both PvE and PvP. This tier list is updated based on new releases and meta shifts.
Best Sync Pairs in Pokémon Masters EX (Overall Tier List)
S-Tier: Best Sync Pairs for All Game Modes
- Red & Charizard (Fire): high DPS, excellent synergy.
- Leon & Eternatus (Dragon/Poison): Great AoE damage.
- Cynthia & Mega Garchomp (Ground/Dragon): powerful striker.
A-Tier: Strong but Situational Sync Pairs
- Gloria & Zacian (Steel): Strong but needs support.
- Lillie & Lunala (Ghost/Psychic): High Special Attack.
- Steven & Mega Metagross (Steel): Good tank but requires setup.
B-Tier: Good but Outclassed Sync Pairs
- Blue & Mega Pidgeot (Flying): decent but lacks longevity.
- Diantha & Mega Gardevoir (Fairy/Psychic)—solid, but niche.
C-Tier: Average Sync Pairs with Limited Viability
- Misty & Starmie (Water) Good support but overshadowed.
- Erika & Vileplume (Grass/Poison): Status effects but lacks damage.
D-Tier: Weakest Sync Pairs with Low Impact
- Brock & Onix (Rock/Ground): Too slow for competitive play.
- Lt. Surge & Electrode (Electric): Low overall effectiveness.
Role-Based Tier Lists
Best Damage Dealers (Strikers) Tier List
- Red & Charizard (Fire): Best for raw power.
- N & Reshiram (Dragon/Fire): Strong special attacker.
Best Support Sync Pairs Tier List
- Skyla & Swanna (Flying): Great healing and speed boost.
- Serena & Delphox (Fire/Psychic): Strong debuff support.
Best Tech Sync Pairs Tier List
- Koga & Crobat (Poison/Flying): Toxic stall strategy.
- Raihan & Duraludon (Steel/Dragon): weather-based synergy.
Elemental & Type-Based Tier Lists
Best Sync Pairs by Type
- Best Fire-Type: Red & Charizard
- Best Water-Type: May & Swampert
- Best Electric-Type: Volkner & Luxray
- Best Dragon-Type: Lance & Dragonite
- Best Psychic-Type: Lillie & Lunala
- Best Ghost-Type: Morty & Mega Banette
F2P (Free-to-Play) & Beginner-Friendly Tier List
Best Free Sync Pairs for Beginners
- Rosa & Serperior (Grass)—Great free tank.
- Hilbert & Samurott (Water): Good offensive unit.
Top Sync Pairs Available Without Spending Gems
- Professor Oak & Mew (Psychic): Versatile, solid stats.
- Player & Pikachu (Electric)—Starter-friendly.
How to Build a Strong Team Without Premium Units
F2P players should focus on high synergy sync pairs, using event rewards and login bonuses to build a competitive team.
Event-Specific & Legendary Sync Pair Tier Lists
Best Legendary Sync Pairs
- Giovanni & Mewtwo (Psychic): Strong single-target striker.
- Lance & Dragonite (Dragon/Flying): high damage, reliable tank.
Best Seasonal Sync Pairs
- Holiday Jasmine & Ampharos (Electric): Unique healer-striker hybrid.
- Summer Lyra & Jigglypuff (Fairy/Normal): Status-inflicting support.
Best Sync Pairs for Battle Villa
- Lana & Araquanid (Water/Bug): defensive playstyle.
- Misty & Starmie (Water): Great healing and evasion boost.
Best Sync Pairs for Champion Stadium
- Iris & Haxorus (Dragon): consistent DPS, good AoE.
- Cynthia & Garchomp (Dragon/Ground): Multi-purpose attacker.
Sync Pair Synergies & Team Combinations
Best Team Compositions for Beginners
- Rosa & Serperior (Tank); Red & Charizard (Striker); Skyla & Swanna (Support)
- Lillie & Lunala (Striker), Sabrina & Alakazam (Buff), + Erika & Vileplume (Status Effect)
How to Build an Optimal Team for Different Game Modes
- PvE Focused Teams: Best for story mode and co-op battles.
- PvP Focused Teams: Best for competitive battles with high burst damage.
Recent & Upcoming Sync Pair Updates

Latest Pokémon Masters EX Sync Pair Additions
- Ash & Pikachu (Electric): Coming soon!
- Leon & Charizard (Fire/Dragon)—Powerhouse.
Predictions for Upcoming Sync Pairs
- Possible Pokémon Scarlet & Violet tie-in sync pairs.
- More Galar region sync pairs are expected in 2024.
How to Upgrade & Maximize Sync Pairs
Leveling Up Sync Pairs
- Use training items from battles and events.
Unlocking EX Forms and Power-Ups
- Some sync pairs have EX versions, increasing their strength significantly.
Best Strategies to Farm Resources
- Daily training areas.
- Completing event challenges.
Conclusion
This Pokémon Masters EX Tier List is designed to help you pick the best sync pairs for different game modes. Keep an eye on meta updates, build strong synergies, and optimise your team for better battles.
FAQs
What are the best sync pairs for PvE vs. PvP?
For PvE, focus on balanced teams. For PvP, prioritise burst damage sync pairs.
How often is the tier list updated?
The tier list is updated regularly based on meta changes.
Are event sync pairs worth pulling?
Yes! Limited-time sync pairs often have unique abilities.
How do I get the strongest sync pairs as an F2P player?
Use free gems, events, and scout tickets wisely!